Deleted
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Post by Deleted on Nov 13, 2012 12:31:32 GMT -5
Hello all;
I have a question that has bothered me for a year. This is regarding obsidian and/or manmade glass. Clearly these both 'off gas'. I started adding broken bottles to my tumbles as filler and I started having bulging caps. Of course, this was predictable. I have been on this forum for long enough to expect it!
My question is, "but why?"
What is this gas, and from where does it emenate?
Is it a chemical reaction between the grit and the glass?
Has anyone played with pH in the barrel to see if it controls or exacerbates the gas?
Thank you.
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peachfront
fully equipped rock polisher
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Post by peachfront on Nov 13, 2012 13:27:36 GMT -5
I have wondered the same thing. Glass bottle bits are REALLY gassy. If I use them I have to burp the barrel every day or maybe every 48 hours if I just use a few.
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Post by catmandewe on Nov 13, 2012 14:55:46 GMT -5
I just use stronger barrels and add them to create pressure, it is along the same lines as a pressure cooker, stuff cooks faster in a pressure cooker, thus rocks should finish faster in a pressure tumbler.
Have no idea what causes the gas though, would be interesting to find out. I hope someone knows.............Tony
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The Dad_Ohs
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Post by The Dad_Ohs on Nov 13, 2012 16:13:03 GMT -5
you could always try grinding a couple pills of Gas-x or beano and add it to your tumbler to see if it stops the gas build up. or any other anti gas forming item that you may know of.
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Deleted
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Post by Deleted on Nov 13, 2012 18:34:07 GMT -5
Oddly, Gas-X is Simethicone. A silicone based anti-foam agent. Likely what it does is make the gas easier to pass because of the lack of foaming. Might work in our systems when foaming is an issue.
Daniel, your idea of using super hot water to cool and pull vacuum is terrific!
I do doubt that much gas is dissolved in glass made in an atmospheric environment. At molten glass temperatures the amount of gases present are minimal. They have expanded to such a great degree as to be near vacuum. Just like your hot water expands and contracts later upon cooling. Obsidian made molten underground could easily have lots of soluble gasses. But it seems that man-made glass off gasses more!
If I ever get my MJR running again, I am going to test pH with man made glass to see if there is a difference between acidic/neutral/basic solutions. I guess, Azrockgeek and I need to kill a couple of six packs to have bottles to work with!
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Dora
spending too much on rocks
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Post by Dora on Nov 13, 2012 21:21:31 GMT -5
Organic matter seems to cause it because dying and decaying is known to produce a gas buildup and movement and higher temperatures could speed the process. Some rocks could have LOTS of invisible organic matter hitchhiking on them and some rocks might have some encrusted, or on the inside as well. I’m sure that there could be many other processes contributing to it too. So that’s why it’s always a good idea to wash rocks well before tumbling them. Checking the barrels after the first days could help noticing if we will be having this problem. If we notice the problem adding a teaspoon of baking soda for each 3 pounds of rocks will solve the problem. When I saw your post I liked your idea about pH and went to test my (obsidian) slurry to test out its pH. Came out neutral, I will check it out throughout its other stages to see if it changes. I think that different combinations of rocks and grit during different stages could create different results. I have a Milwaukee ph tester but could not use it because the slurry will damage it, so I used a Rapitest mini pH/Moisture tester for plant soil. I’m sure that there are better testers out there to get more accurate readings but probably much more $$$! Thanks this was a very interesting and motivational post.
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custommike
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Post by custommike on Nov 15, 2012 13:02:23 GMT -5
I did a bit of looking around. Looks like obsidian is mainly silicon dioxide and can produce a gas (not sure of the name) when combined with fluorine, commonly found in tap water. It would not surprise me at all if tumbling was able to break down obsidian to the point where it was able to bond with fluorine producing the gas.
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Deleted
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Post by Deleted on Nov 18, 2012 23:42:33 GMT -5
OK, what did I miss? This thread is a very weird read now!
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Dora
spending too much on rocks
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Post by Dora on Nov 19, 2012 0:02:02 GMT -5
Don't worry shotgunner, everything is fine and good.
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Minnesota Daniel
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Post by Minnesota Daniel on Nov 19, 2012 1:01:27 GMT -5
I got a little off track, so I removed my "too long" posts.
What I should not have deleted was that I fill my barrels with the hottest water I can get out of the taps. It has less dissolved gas in it, and the barrels contract when it cools down, leaving more room for off-gassing. I'm pretty sure that the over-the-counter meds you can take for a gassy stomach aren't going to work in a tumbling barrel. Different processes.
I did look it up and apparently the sheen obsidians are that way from teeny tiny bubbles that happened when the liquid obsidian contacted water. The bubbles are water vapor. I have no idea if they make the barrel bulge, or if there are also other gasses.
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Deleted
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Post by Deleted on Nov 19, 2012 20:00:00 GMT -5
Thanks Daniel & Dora.
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jamesp
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Post by jamesp on Dec 10, 2012 14:03:01 GMT -5
I am trying to figure out the gas problem It is happenning to me on all 3 barrels.Can not get a ph test as water is too dirty.My stones have a lot of limestone attached.I am guessing an overly alkaline brew.And it smells a bit like concrete....?It gases up quick and then rubber caps bulge.So would you add vinegar?It may not be PH...I may do well using litmus paper,it may not care if water is mucky.These barrels run glass on occasion,and they bulge.But never popped the cap off. This is a lot of pressure.The rocks are agate and limestone covered silicified coral.I will try vinegar for a few hours in one barrel..Maybe the cap will draw inward,as the often do.Thanks in advance
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Deleted
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Post by Deleted on Dec 10, 2012 14:11:25 GMT -5
jamesp if you have limestone in the barrell then the pH is 8.0-8.1. That is because a saturated solution of CaCO3 is this pH. If you have an acid constituent, like vinegar, the limestone will come apart and offgas CO2 which is likely why you have gas buildup, because of some low pH minerals reacting with the limestone.
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jamesp
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Post by jamesp on Dec 11, 2012 4:41:14 GMT -5
The vinegar is not the solution.Any other ideas?Too much water?Clean rocks and start over?Never had so much pressure before over a 24 hour period.I did have the water about a half an inch over the rocks.Normally i run on the dry side(and pasty).
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jamesp
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Post by jamesp on Dec 11, 2012 5:02:22 GMT -5
A note about the vinegar.I added a heavy dose - 3 cups in a 16 pound cap barrel.After an hour i had a slight vacumn.After another hour it started to build pressure.But the vacumn surprised me.... On the subject of glass/obsidian-captured bubbles could have extreme pressure which equals large volumes of gas.These small bubbles release their contents as the grit cuts them open.You can fill 1000's of baloons from a small 3000psi nitrogen tank.Our tumbler barrels start freaking out at 10 psi.I could understand gas build up being completely independent of PH.Probably a dozen chemical reactions that could cause pressure.
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jamesp
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Post by jamesp on Dec 11, 2012 5:20:47 GMT -5
Run off from peat rich swamps cut through limestone bedrock leaving 50 foot bluffs.PH 5 is common for the run off water flowing into the river during the wet season.That leaves a lot of undissolvable silicifications behind laying on the bottom of the river.During the hot season the rivers drop exposing those treasures.PH has a huge influence on our ecosystem.I respect the power of PH.I am guessing that gases formed from low PH mixing with high PH contents within the tumbler barrel are causing havoc.The highest pressure was in the 16 pound cap tumbler that had 12 pounds of cooked coral...Added 4 pounds of river agates to get 16 pounds total.Maybe it's the cooked coral. Wondering out loud
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Post by mohs on Dec 11, 2012 11:06:52 GMT -5
Interesting subject
rocks are full of oxygen molecules... no ? I mean.. isn't 1 of the the chemical composition of silica --oxygen ? so as the rocks break down in the tumble the oxygen is getting released oxygen molecules having no where to go in a sealed container a build of gas results
now here's the scary part if rocks only contained oxygen as a gas and pure oxygen is flammable
well... I think you see where I'm going with a bulging barrel of pure oxygen.... :help:
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jamesp
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Post by jamesp on Dec 11, 2012 11:20:39 GMT -5
You are right St.EdMo,interesting and complicated.Oxygen and dozens of other compounds,mixes,elements etc.No simple answers.Let's hope were not making pipe bmbs!
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Post by rockpickerforever on Dec 11, 2012 11:24:32 GMT -5
You are correct, EdMo. Give that man a cookie! I always thought that SiO 2 meant two oxygen atoms for each silicon atom. Yet, accordng to Wiki en.wikipedia.org/wiki/Silicon_dioxide, there are FOUR oxygen atoms to each silicon atom, arranged in a three-sided pyramid around the silicon. Go figure... No wonder I flunked chemistry! But anyways, YES, lots of oxygen. Can see how gas could be released by breaking the molecules down, even without addition of beans or sugar. Jean
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Post by mohs on Dec 11, 2012 11:59:51 GMT -5
I've thoroughly have tested the pure oxygen theory I usually have a burning cigar dangling from me when I burp my barrel
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